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| POLY
TETRA FLUORO ETHYLENE: ______________________________________________ |
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PTFE is high performance
engineering speciality polymer invented by Dr. Roy J.
Plunkett at DU Pont's Jackson Laboratory, New Jersey,
US, on 6th April 1938. As the polymer was found to have
exceptional properties with regards to chemical inertness,
heat resistance & frictional properties; developmental
manufacturing began in 1943 with joint efforts of kinetic
Engineering Inc., USA & E.I. du pont de Nemours
& Co. Inc. USA. The commercial production went operational
by E.I. du Pont de Nemours & Co. Inc., USA in 1948.
The worldwide consumption of PTFE is around 45,000 Tones
in 1977 & expected to grow at the rate of 10% per
annum.
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| POLYMER
SCIENCE: ________________________________________________________ |
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TFE Monomer is generally
manufactured by synthesis of Calcium Fluoride (Fluorospar),
Sulphuric Acid & Chloroform. The polymerisation
of TFE is carried
out in carefully controlled conditions to form PTFE.
Due
to presence of stable & strong C-F bonds, PTFE
molecule possesses outstanding chemical inertness, high
heat resistance & remarkable electrical insulation
characteristics; in addition to excellent frictional
properties.
PTFE
polymer is produced worldwide on commercial basis by
a number of chemical industries under different registered
tradenames such as Du Pont (TEFLON), ICI (FLUON), Hoechst
(HOSTAFLON), Montefluos (ALGOFLON), Daikin (POLYFLON),
HFL (HIFLON), Nitto Chemicals (TETRAFLON).
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The Chemical structure of PTFE is: 
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| GENERAL
PROPERTIES :
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PTFE is polymer
which is extensively used in chemical, mechanical, electronic
& electrical industries due to its unique characteristics.
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Chemical inertness to all known chemicals, however
attacked by molten alkali metals, chlorine, trifluorides,
fluorine & related fluorine complexes of elevated
temperature & pressure.
- Resistance
to solvents, insoluble in all solvents upto 260°C.
Certain high fluorinated oils swell & dissolve
PTFE at temperature
close to crystalline melting point.
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Wide operating temperature range -250°C t +260°C,
at atmospheric pressure.
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Lowest coefficient of friction among all known metals
& nonmetals.
- Nontoxic
& antistick properties.
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Negligible water absorption
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Nonflammable
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Resistance to radiations, electrical properties remain
practically unchanged during & after irradiation,
both in air & vacuum.
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Excellent weathering resistance.
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Outstanding electrical/ insulating properties over
wide frequency range.
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